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Friends View All (0) [none added] - try making friends in the Forum or TV Games section Chuck Premiered: Sep. 24, 2007 Network: NBC Random Fun Fact: Natalie Martinez was to join the cast after the pilot episode as Kayla Hart, a love interest for Chuck. Martinez appeared in the cast promotional pictures but her character was written out… [show all]Natalie Martinez was to join the cast after the pilot episode as Kayla Hart, a love interest for Chuck. Martinez appeared in the cast promotional pictures but her character was written out before she could appear on the show. [hide]